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(Solved): 11.1. At 25\deg C and atmospheric pressure the volume change of mixing of binary liquid mixtures of ...



11.1. At

25\deg C

and atmospheric pressure the volume change of mixing of binary liquid mixtures of species

I

and 2 is given by the equation

\Delta V=x_(1)x_(2)(45x_(1) 25x_(2))

where

\Delta V

is in

cm^(3)*mol^(-1)

. At these conditions,

V_(1)=110

and

V_(2)=90cm^(3)*mol^(-1)

. Determine the partial molar volumes

/bar (V)_(1)

and

/bar (V)_(2)

in a mixture containing 40 -mol-

%

of species 1 at the given conditions.



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