200 ANAL0498: Separating Selected Metal Cations by Paper Chromatograpny 4. A student in a hurry decides to let the solvent travel only half way up the chromatographic paper in Chromatogram 2. Predict the effect of this procedural change on the resolution of the cations in the standard mixture. 5. (a) Based on your calculated
R_(f)
values, which cation(s) formed weakly charged complexes? (b) How does the presence of
HCl
affect the charges on the complexes? (c) If
10mL
of water, instead of
10mL
of
6MHCl
, were added to the acetone, how would it affect the charges on the weakly charged complexes identified in (a)? What would be the effect on their
R_(f)
values? How would this affect the resolution of the chromatography? (d) Explain whether or not the substitution of water for
6MHCl
would cause similar changes in the charges of the complexes that are strongly charged in the acetone
/6MHCl
solvent system. A student in a hurry decides to let the solvent travel only half way up the chromatographic paper in Chromatogram 2. Predict the effect of this procedural change on the resolution of the cations in the standard mixture. (a) Based on your calculated
R_(f)
values, which cation(s) formed weakly charged complexes? (b) How does the presence of
HCl
affect the charges on the complexes? (c) If
10mL
of water, instead of
10mL
of
6MHCl
, were added to the acetone, how would it affect the charges on the weakly charged complexes identified in (a)? What would be the effect on their
R_(f)
values? How would this affect the resolution of the chromatography? (d) Explain whether or not the substitution of water for
6MHCl
would cause similar changes in the charges of the complexes that are strongly charged in the acetone
/6MHCl
solvent system.