A 11.6 g sample of copper (Cu, c = 0.385 J/g0C) is heated to 100.00C and placed in 72.2 g of water (H2O, c = 4.184 J/g0C) in a coffee cup calorimeter. After the copper and water come to thermal equilibrium, the temperature is 27.2 0C. What was the inital temperature of the water before the metal was added? (SHOW WORK)