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(Solved): A certain half-reaction has a standard reduction potential E_(red)^(0)=+0.76V. An engineer proposes ...



A certain half-reaction has a standard reduction potential

E_(red)^(0)=+0.76V

. An engineer proposes using this half-reaction at the cathode of a galvanic cell that must provide at least

1.20V

of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the cathode of the cell. \table[[Is there a minimum standard reduction,yes, there is a minimum.],[potential that the half-reaction used at,],[the anode of this cell can have?,],[If so, check the "yes" box and calculate,],[the minimum. Round your answer to 2,],[decimal places. If there is no lower,],[limit, check the "no" box.,no minimum]] ofo Standard reduction potentials at

25\deg C

\table[[

O_(2)(g)+2H^(+)(aq)+2e^(-)->H_(2)O_(2)(aq)

,0.695],[

MnO_(4)^(-)(aq)+2H_(2)O(l)+3e^(-)->MnO_(2)(s)+4OH^(-)(aq)

,0.595],[

I_(2)(s)+2e^(-)->2I^(-)(aq)

,0.536],[

Cu^(+)(aq)+e^(-)->Cu(s)

,0.521],[

O_(2)(g)+2H_(2)O(l)+4e^(-)->4OH^(-)(aq)

,0.401],[

Cu^(2+)(aq)+2e^(-)->Cu(s)

,0.342],[

HSO_(4)^(-)(aq)+3H^(+)(aq)+2e^(-)->H_(2)SO_(3)(aq)+H_(2)O(I)

,0.172],[

SO_(4)^(2-)(aq)+4H^(+)(aq)+2e^(-)->SO_(2)(g)+2H_(2)O(I)

,0.172],[

Cu^(2+)(aq)+e^(-)->Cu^(+)(aq)

,0.153],[

Sn^(4+)(aq)+2e^(-)->Sn^(2+)(aq)

,0.151],[

2H^(+)(aq)+2e^(-)->H_(2)(g)

,0.000],[

Fe^(3+)(aq)+3e^(-)->Fe(s)

,-0.037],[

Pb^(2+)(aq)+2e^(-)->Pb^(2)(s)

,-0.126],[

CrO_(4)^(2-)(aq)+4H_(2)O(l)+3e^(-)->Cr(OH)_(3)(s)+5OH^(-)(aq)

,-0.13],[

Sn^(2+)(aq)+2e^(-)->Sn(s)

,-0.138],[

N_(2)(g)+5H^(+)(aq)+4e^(-)->N_(2)H_(5)^(+)(aq)

,-0.214]]

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