Discuss the basic postulates of VSEPR theory. Explain with examples. Predict the shapes and hybridizations of
PCl_(5),BrF_(5),ICl_(6)
and
xeF_(2)
and
xeF_(4)
molecules Discuss the significance of Heisenberg's uncertainty principle. What is penetration effect of an atom? Derive the integrated rate law for 1 st order reaction. Hence draw the plot and explain it. Find out the expression for the half-life. Does this reaction reach the completion For a first order reaction
A->B,64.7%
reactant remains undecomposed after 751 seconds. Then calculate the half-life of the reaction. What would be time required to decompose
90%
of
A
. Why do Boron and Carbon in their ground state show lower ionization energies than expected? Predict the structures of
SF_(4),CIF_(3)
and
I_(3)
molecules. Explain why increase in polarizability of anions from
Cl
to
I
, the colors of the concerned compounds increases.