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(Solved): The following reaction illustrates the use of a cyano compound with an organolithium reagent. Draw a ...



The following reaction illustrates the use of a cyano compound with an organolithium reagent. Draw a curved arrow mechanism of the second step of this reaction. Show all intermediate structures.

Draw the expected major product of the following reduction.

H_(2)O

Using the curved arrow formalism, draw a mechanism to show the following isomerization reaction. Draw the expected major product of the following reaction.

Propose a synthesis of the following ketone using any reagents, but you must start from ethyl acetoacetate. Based on the following scheme, draw the structures of compounds

A-F

, as well as the reagents

x

and

Y

. Based on the following scheme, draw the structures of compounds

H

and

I

.

->_(2.)^(1.LDA,-78^(@)C)->_(H_(2)O)^(H_(3)O^( ))H

NaOH

H_(3)O^( )

heat There are multiple methods to convert a primary amide to a nitrile. Your textbook (section 20.7) shows the mechanism for this conversion using thionyl chloride. Using the mechanism provided in the textbook as a guide, propose a mechanism for the same conversion using acetic anhydride (a carboxylic acid anhydride). Propose a synthesis of the following ketone using any reagents, but you must start from ethyl acetoacetate. Based on the following scheme, draw the structures of compounds

A-F

, as well as the reagents

x

and

Y

.



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